In the field of high data rate wireless communications, localization issues play a key role in achieving energy-efficient communication and geographic routing. time-difference of arrival (TDOA)-based localization methods present numerous advantages. In this paper, a new method of TDOA estimation is proposed. With this method, unlike conventional TDOA measurements, it is possible to perform communication and localization at the same time by using a multi-input single-output system. By transmitting ultra-wide-band orthogonal frequency-division multiplexing signals using spatial diversity, it is possible to extract TDOA from interference patterns in spectral domain. In addition, increasing the precision of localization is also studied using a multi-band approach. This whole study is made within the framework of the WiGig alliance specifications; however, it is compatible with other standards.