Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry

A heterochiral 1,3,5-benzene tricarboxamide (BTA) monomer, derived from valine dodecyl ester, forms long rods in cyclohexane whilst its homochiral analogue assembles into dimers only at the same concentration. This highly original assembly behaviour is related to the destabilization of the dimeric structure containing the two heterochiral monomers as corroborated by a combined experimental and computational study.

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Chimie

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Caumes_2016_Tuning_the.pdf (659.74 Ko)

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https://hal.sorbonne-universite.fr/hal-01394304

Soumis le : mercredi 9 novembre 2016-10:49:15

Dernière modification le : jeudi 11 avril 2024-13:08:14

Archivage à long terme le : mardi 14 mars 2017-23:07:16

Dates et versions

hal-01394304 , version 1 (09-11-2016)

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HAL Id : hal-01394304 , version 1
DOI : 10.1039/C6CC07325E

Citer

Xavier Caumes, Arianna Baldi, Geoffrey Gontard, Patrick Brocorens, Roberto Lazzaroni, et al.. Tuning the structure of 1,3,5-benzene tricarboxamide self-assemblies through stereochemistry. Chemical Communications, 2016, 52 (91), pp.13369 - 13372. ⟨10.1039/C6CC07325E⟩. ⟨hal-01394304⟩

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