Single ion magnets based on lanthanoid polyoxomolybdate complexes - Sorbonne Université Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2016

Single ion magnets based on lanthanoid polyoxomolybdate complexes

Résumé

Polyoxometalate (POM) chemistry has recently offered excellent examples of single ion magnets (SIMs) and molecular spin qubits. Compared with conventional coordination compounds, POMs provide rigid and highly symmetric coordination sites. However, all POM-based SIMs reported to date exhibit a very limited range of possibilities for chemical processability. We present herein two new families of POM-based SIMs which are soluble in organic solvents: [Ln(β-Mo8O26)2]5− {LnIII = Tb, Dy, Ho, Er, Tm and Yb} and the functionalised POMs [Ln{Mo5O13(OMe)4NNC6H4-p-NO2}2]3− {LnIII = Tb, Dy, Ho, Er, Yb and Nd}. In addition, these two families represent the first SIMs based on polyoxomolybdates. A magneto-structural analysis of these families is presented, which is based on an effective crystal field model, and compared with the results reported in analogous lanthanoid SIMs based on polyoxotungstates.

Domaines

Chimie
Fichier principal
Vignette du fichier
Baldovi_2016_Single_ion_magnets.pdf (897.45 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-01397208 , version 1 (15-11-2016)
hal-01397208 , version 2 (21-12-2016)

Identifiants

Citer

José J. Baldoví, Yan Duan, Carlos Bustos, Salvador Cardona-Serra, Pierre Gouzerh, et al.. Single ion magnets based on lanthanoid polyoxomolybdate complexes. Dalton Transactions, 2016, 45 (42), pp.16653 - 16660. ⟨10.1039/C6DT02258H⟩. ⟨hal-01397208v1⟩
362 Consultations
139 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More