A. G. Redfield, W. Fite, and H. E. Bleich, Precision High Speed Current Regulators for Occasionally Switched Inductive Loads, Review of Scientific Instruments, vol.116, issue.5, pp.710-715, 1968.
DOI : 10.1103/PhysRev.133.A1616

R. Kimmich, Field-cycling in NMR relaxation spectroscopy: applications in biological, chemical and polymer physics, Bull. Magn. Reson, vol.1, pp.195-217, 1980.

F. Noack, NMR field-cycling spectroscopy: principles and applications, Progr. Nucl. Magn. Reson. Spectrosc, vol.18, issue.171, 1986.
DOI : 10.1016/0079-6565(86)80004-8

F. Noack, Basics and novel aspects of NMR field-cycling spectroscopy, Bull. Ampere, vol.175, pp.18-35, 1994.

R. Kimmich and E. , Field-cycling NMR relaxometry, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.44, issue.3-4, pp.257-320, 2004.
DOI : 10.1016/j.pnmrs.2004.03.002

R. Kimmich and N. Fatkullin, Self-diffusion studies by intra- and inter-molecular spin-lattice relaxometry using field-cycling: Liquids, plastic crystals, porous media, and polymer segments, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.101, pp.18-50, 2017.
DOI : 10.1016/j.pnmrs.2017.04.001

K. Victor, V. Kavolius, and R. G. Bryant, Magnetic relaxation dispersion probe, Journal of Magnetic Resonance, vol.171, issue.2, pp.253-257, 2004.
DOI : 10.1016/j.jmr.2004.08.025

S. Wagner, T. R. Denisen, T. Rayner, and R. G. Bryant, High-Resolution Magnetic Relaxation Dispersion Measurements of Solute Spin Probes Using a Dual-Magnet System, Journal of Magnetic Resonance, vol.140, issue.1, pp.140-172, 1999.
DOI : 10.1006/jmre.1999.1811

A. G. Redfield, High-resolution NMR field-cycling device for full-range relaxation and structural studies of biopolymers on a shared commercial instrument, Journal of Biomolecular NMR, vol.50, issue.2, pp.152-177, 2012.
DOI : 10.1103/PhysRevLett.50.1807

Y. Gossuin, Z. Serhan, L. Sandiford, D. Henrard, T. Marqardsen et al., Sample Shuttling Relaxometry of Contrast Agents: NMRD Profiles above 1 T with a Single Device, Applied Magnetic Resonance, vol.293, issue.3, pp.47-237, 2016.
DOI : 10.1016/j.jmmm.2005.01.070

URL : https://hal.archives-ouvertes.fr/hal-01266671

S. F. Cousin, P. Kaderavek, B. Haddou, C. Charrier, T. Markadsen et al., High-resolution two-field nuclear magnetic resonance spectroscopy, Physical Chemistry Chemical Physics, vol.207, issue.91, pp.33187-33194, 2016.
DOI : 10.1016/j.jmr.2010.09.014

URL : https://hal.archives-ouvertes.fr/cea-01393871

G. Liu, Y. Li, and J. Jonas, Confined geometry effects on reorientational dynamics of molecular liquids in porous silica glasses, The Journal of Chemical Physics, vol.4, issue.9, pp.95-6892, 1991.
DOI : 10.1080/00268978500103061

J. Korb, S. Xu, and J. Jonas, Confinement effects on dipolar relaxation by translational dynamics of liquids in porous silica glasses, The Journal of Chemical Physics, vol.98, issue.3, pp.98-2411, 1993.
DOI : 10.1111/j.1151-2916.1989.tb06043.x

J. Korb, M. Whaley-hodges, and R. G. Bryant, Translational diffusion of liquids at surfaces of microporous materials: Theoretical analysis of field-cycling magnetic relaxation measurements, Physical Review E, vol.31, issue.2, pp.1934-1935, 1997.
DOI : 10.1209/0295-5075/31/8/006

J. Korb, M. Whaley-hodges, T. Gobron, and R. G. Bryant, Anomalous surface diffusion of water compared to aprotic liquids in nanopores, Physical Review E, vol.2, issue.3, pp.3097-3106, 1999.
DOI : 10.1007/BF02457137

S. Stapf, X. Ren, E. Talnishnikh, and B. Blümich, Spatial distribution of coke residues in porous catalyst pellets analyzed by field-cycling relaxometry and parameter imaging, Magnetic Resonance Imaging, vol.23, issue.2, pp.383-386, 2005.
DOI : 10.1016/j.mri.2004.11.036

H. Jaffel, J. Korb, J. P. Ndobo-epoy, V. Morin, and J. Guicquero, Probing Microstructure Evolution during the Hardening of Gypsum by Proton NMR Relaxometry, The Journal of Physical Chemistry B, vol.110, issue.14, pp.7385-7391, 2006.
DOI : 10.1021/jp058276m

H. Jaffel, J. Korb, J. P. Ndobo-epoy, J. Guicquero, and V. Morin, Multi-scale Approach Continuously Relating the Microstructure and the Macroscopic Mechanical Properties of Plaster Pastes during Their Settings, The Journal of Physical Chemistry B, vol.110, issue.37, pp.18401-18407, 2006.
DOI : 10.1021/jp062832a

F. Barberon, J. Korb, D. Petit, V. Morin, and E. Bermejo, Probing the Surface Area of a Cement-Based Material by Nuclear Magnetic Relaxation Dispersion, Physical Review Letters, vol.34, issue.11, pp.90-116103, 2003.
DOI : 10.1063/1.1731684

A. Plassais, M. Pomies, N. Lequeux, J. Korb, D. Petit et al., Microstructure evolution of hydrated cement pastes, Physical Review E, vol.9, issue.4, pp.41401-041408, 2005.
DOI : 10.1021/jp031174g

URL : https://hal.archives-ouvertes.fr/hal-00166391

J. Korb, B. Nicot, A. Louis-joseph, S. Bubici, and G. Ferrante, Dynamics and Wettability of Oil and Water in Oil Shales, The Journal of Physical Chemistry C, vol.118, issue.40, pp.23212-23218, 2014.
DOI : 10.1021/jp508659e

J. Korb, L. Malier, F. Cros, S. Xu, and J. Jonas, Surface Dynamics of Liquids in Nanopores, Physical Review Letters, vol.104, issue.11, pp.77-2312, 1996.
DOI : 10.1021/ja00381a009

S. G. Godefroy, J. Korb, M. Fleury, and R. G. Bryant, Surface nuclear magnetic relaxation and dynamics of water and oil in macroporous media, Physical Review E, vol.99, issue.2, pp.21605-021612, 2001.
DOI : 10.1142/0270

S. G. Godefroy, M. Fleury, F. Deflandre, and J. Korb, Temperature Effect on NMR Surface Relaxation in Rocks for Well Logging Applications, The Journal of Physical Chemistry B, vol.106, issue.43, pp.11183-11190, 2002.
DOI : 10.1021/jp0213452

J. Korb, G. Freiman, B. Nicot, and P. , Dynamical surface affinity of diphasic liquids as a probe of wettability of multimodal porous media, Physical Review E, vol.36, issue.6, pp.61601-061612, 2009.
DOI : 10.1063/1.2183311

J. Korb, NMR and nuclear spin relaxation of cement and concrete materials, Current Opinion in Colloid & Interface Science, vol.14, issue.3, pp.192-202, 2009.
DOI : 10.1016/j.cocis.2008.10.004

P. J. Mcdonald, J. Korb, J. Mitchell, and L. Monteilhet, Surface relaxation and chemical exchange in hydrating cement pastes: A two-dimensional NMR relaxation study, Physical Review E, vol.327, issue.1, pp.11409-011409, 2005.
DOI : 10.1103/PhysRev.94.630

L. Monteilhet, J. Korb, P. J. Mitchell, and P. J. Mcdonald, Observation of exchange of micropore water in cement pastes by two-dimensional T2?T2 nuclear magnetic resonance relaxometry, Phys. Rev. E, vol.74, pp.6404-06409, 2006.

K. E. Washburn and P. T. Callaghan, Tracking Pore to Pore Exchange Using Relaxation Exchange Spectroscopy, Physical Review Letters, vol.97, issue.17, pp.97-17502, 2006.
DOI : 10.1016/S0730-725X(03)00144-9

M. Fleury and J. Soualem, Quantitative analysis of diffusional pore coupling from T2-store-T2 NMR experiments, Journal of Colloid and Interface Science, vol.336, issue.1, p.250259, 2009.
DOI : 10.1016/j.jcis.2009.03.051

J. Mitchell, M. D. Hürlimann, and E. J. Fordham, A rapid measurement of : The DECPMG sequence, Journal of Magnetic Resonance, vol.200, issue.2, pp.198-206, 2009.
DOI : 10.1016/j.jmr.2009.07.002

S. Bubici, J. P. Korb, J. Kucerik, and P. Conte, Evaluation of the surface affinity of water in three biochars using fast field cycling NMR relaxometry, Magnetic Resonance in Chemistry, vol.72, issue.5, pp.54-365, 2016.
DOI : 10.3311/PPch.7188

K. Victor, J. Korb, and R. G. Bryant, Translational Dynamics of Water at the Phospholipid Interface, The Journal of Physical Chemistry B, vol.117, issue.41, pp.12475-12478, 2013.
DOI : 10.1021/jp407149h

S. H. Koenig and R. D. Brown, Field-cycling relaxometry of protein solutions and tissue: Implications for MRI, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.22, issue.6, pp.22-487, 1990.
DOI : 10.1016/0079-6565(90)80008-6

J. Korb, G. Diakova, Y. Goddard, and R. G. Bryant, Relaxation of protons by radicals in rotationally immobilized proteins, Journal of Magnetic Resonance, vol.186, issue.2, pp.176-181, 2007.
DOI : 10.1016/j.jmr.2007.02.006

J. Korb, Y. Goddard, J. Pajski, G. Diakova, and R. G. Bryant, Extreme-Values Statistics and Dynamics of Water at Protein Interfaces, The Journal of Physical Chemistry B, vol.115, issue.44, pp.12845-12858, 2011.
DOI : 10.1021/jp2053426

D. Grebenkov, Y. Goddard, G. Diakova, J. Korb, and R. G. Bryant, Dimensionality of Diffusive Exploration at the Protein Interface in Solution, The Journal of Physical Chemistry B, vol.113, issue.40, pp.13347-13356, 2009.
DOI : 10.1021/jp9048082

G. Diakova, J. Korb, and R. G. Bryant, The magnetic field dependence of water T1 in tissues, Magnetic Resonance in Medicine, vol.13, issue.1, pp.272-277, 2012.
DOI : 10.1002/jmri.1076

W. D. Rooney, G. Johnson, X. Li, E. R. Cohen, S. G. Kim et al., Magnetic field and tissue dependencies of human brain longitudinal1H2O relaxation in vivo, Magnetic Resonance in Medicine, vol.181, issue.2, pp.308-318, 2007.
DOI : 10.1148/radiology.199.3.8638004

D. M. Bihan, J. Mangin, C. Poupon, S. Pappota, N. Molko et al., Diffusion tensor imaging: Concepts and applications, Journal of Magnetic Resonance Imaging, vol.44, issue.4, pp.534-546, 2001.
DOI : 10.1148/radiology.210.3.r99fe17617

URL : https://hal.archives-ouvertes.fr/hal-00349820

A. Abragam, The Principles of Nuclear Magnetism, 1961.

N. Bloembergen, E. M. Purcell, and R. V. Pound, Relaxation Effects in Nuclear Magnetic Resonance Absorption, Physical Review, vol.32, issue.7, pp.679-712, 1947.
DOI : 10.1109/JRPROC.1944.232049

P. S. Hubbard, Theory of electron-nucleus Overhauser effects in liquids containg free radicals, Proc. R. Soc. Lond. Ser, vol.1, issue.537, 1966.

Y. Ayant, E. Belorisky, J. Alizon, and J. Gallice, Calcul des densit??s spectrales r??sultant d'un mouvement al??atoire de translation en relaxation par interaction dipolaire magn??tique dans les liquides, Journal de Physique, vol.274, issue.10, pp.991-1004, 1975.
DOI : 10.1051/jphys:019750036010099100

J. Korb, S. Godefroy, and M. Fleury, Surface nuclear magnetic relaxation and dynamics of water and oil in granular packings and rocks, Magnetic Resonance Imaging, vol.21, issue.3-4, pp.193-199, 2003.
DOI : 10.1016/S0730-725X(03)00124-3

L. P. Hwang and J. H. Freed, Dynamic effects of pair correlation functions on spin relaxation by translational diffusion in liquids, The Journal of Chemical Physics, vol.63, issue.9, pp.4017-4025, 1975.
DOI : 10.1016/B978-0-12-025508-5.50006-2

Z. Luz, D. Goldfarb, and H. Zimmerman, Nuclear Magnetic Resonance of Liquid Crystals, 1985.

M. Brown, J. Seelig, and U. Haberlen, Structural dynamics in phospholipid bilayers from deuterium spin???lattice relaxation time measurements, The Journal of Chemical Physics, vol.1, issue.11, pp.5045-5053, 1979.
DOI : 10.1038/271182a0

M. F. Brown, Theory of spin-lattice relaxation in lipid bilayers and biological membranes-H-2 and N-14 quadrupolar relaxation, J. Chem. Phys, pp.77-1576, 1982.

M. F. Brown, Unified picture for spin???lattice relaxation of lipid bilayers and biomembranes, The Journal of Chemical Physics, vol.39, issue.6, pp.2832-2836, 1984.
DOI : 10.1016/0022-2364(80)90133-X

J. W. Emsley, Nuclear Magnetic Resonance of liquid crystals, 1985.
DOI : 10.1007/978-94-009-6517-1

J. Seelig, Deuterium magnetic resonance: theory and application to lipid membranes, Quarterly Reviews of Biophysics, vol.78, issue.03, pp.353-418, 1977.
DOI : 10.1021/bi00709a021

M. M. Pike and C. S. Springer, Aqueous shift reagents for high-resolution cationic nuclear magnetic resonance, Journal of Magnetic Resonance (1969), vol.46, issue.2, pp.348-353, 1982.
DOI : 10.1016/0022-2364(82)90153-6

H. M. Mcconnell, Reaction Rates by Nuclear Magnetic Resonance, The Journal of Chemical Physics, vol.28, issue.3, pp.430-431, 1958.
DOI : 10.1063/1.1743445

M. Goldman, T. Tabti, C. Fermon, J. Jacquinot, and G. Saux, A Model for the Influence of Motion on the NMR Lineshape, Journal of Magnetic Resonance, Series A, vol.103, issue.3, pp.288-296, 1993.
DOI : 10.1006/jmra.1993.1168

M. Goldman, A simple formalism for the analysis of NMR in the presence of exchange, Molecular Physics, vol.1, issue.2, pp.301-315, 1995.
DOI : 10.1103/PhysRev.99.559

F. Cros, L. Malier, J. Korb, and F. Chaput, NMR of molecules trapped in sol-gel glasses: Progressive closure of the nanoporosity during drying, Journal de Chimie Physique et de Physico-Chimie Biologique, vol.95, issue.2, pp.95-264, 1998.
DOI : 10.1051/jcp:1998131

J. Jeener, Superoperators in Magnetic Resonance, Adv. Magn. Reson, vol.10, pp.1-51, 1982.
DOI : 10.1016/B978-0-12-025510-8.50006-1

A. D. Bain and B. Berno, Liouvillians in NMR: The direct method revisited, Progress in Nuclear Magnetic Resonance Spectroscopy, vol.59, issue.3, pp.223-244, 2011.
DOI : 10.1016/j.pnmrs.2010.12.002

R. B. Lauffer, Paramagnetic metal complexes as water proton relaxation agents for NMR imaging: theory and design, Chemical Reviews, vol.87, issue.5, pp.901-927, 1987.
DOI : 10.1021/cr00081a003

K. R. Browstein and C. E. Tarr, Importance of classical diffusion in NMR studies of water in biological cells, Physical Review A, vol.151, issue.6, pp.2446-2453, 1979.
DOI : 10.1103/PhysRev.151.264

R. L. Kleinberg, W. E. Kenyon, and P. P. Mitra, Mechanism of NMR Relaxation of Fluids in Rock, Journal of Magnetic Resonance, Series A, vol.108, issue.2, pp.206-214, 1994.
DOI : 10.1006/jmra.1994.1112

J. J. Frippiat, M. Letellier, and P. Levitz, Interaction of water with clay surfaces, Philos. Trans. R. Soc. Lond. A, vol.287, p.311, 1984.

S. Stapf, R. Kimmich, and R. O. Seiter, Proton and Deuteron Field-Cycling NMR Relaxometry of Liquids in Porous Glasses: Evidence for L??vy-Walk Statistics, Physical Review Letters, vol.70, issue.15, pp.75-2855, 1995.
DOI : 10.1016/0021-9797(79)90020-1

D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonkii, Quantum Theory of Angular Momentum, 1988.
DOI : 10.1142/0270

J. Korb, Size effects in the spin relaxation by bounded diffusion in two dimensional systems, The Journal of Chemical Physics, vol.38, issue.2, pp.1061-1062, 1985.
DOI : 10.1063/1.444415

J. Korb, M. Winterhalter, and H. M. Mcconnell, Theory of spin relaxation by translational diffusion in two-dimensional systems, J. Chem. Phys, p.80, 1984.

J. Korb, Multi-scales nuclear spin relaxation of liquids in porous media, Comptes Rendus Physique, vol.11, issue.2, pp.192-203, 2010.
DOI : 10.1016/j.crhy.2010.06.015

I. Solomon, Relaxation Processes in a System of Two Spins, Physical Review, vol.94, issue.2, pp.559-565, 1955.
DOI : 10.1103/PhysRev.94.630

C. C. Lester and R. G. Bryant, Outer coordination sphere: characterization by nuclear magnetic relaxation dispersion, The Journal of Physical Chemistry, vol.94, issue.7, pp.2843-2847, 1990.
DOI : 10.1021/j100370a022

C. F. Polnaszek and R. G. Bryant, Self-diffusion of water at the protein surface: a measurement, Journal of the American Chemical Society, vol.106, issue.2, pp.428-429, 1984.
DOI : 10.1021/ja00314a032

C. F. Polnaszek, D. Hanggi, P. W. Carr, and R. G. Bryant, Nuclear magnetic relaxation dispersion measurement of water mobility at a silica surface, Analytica Chimica Acta, vol.194, pp.311-315, 1987.
DOI : 10.1016/S0003-2670(00)84786-8

A. Mitzithras and J. H. Strange, Diffusion of fluids in confined geometry, Magnetic Resonance Imaging, vol.12, issue.2, pp.261-263, 1994.
DOI : 10.1016/0730-725X(94)91532-6

L. Bocquet and J. L. Barrat, Diffusive Motion in Confined Fluids: Mode-Coupling Results and Molecular-Dynamics Calculations, Europhysics Letters (EPL), vol.31, issue.8, pp.31-455460, 1995.
DOI : 10.1209/0295-5075/31/8/006

H. Chemmi, D. Petit, P. Levitz, R. Denoyel, A. Galarneau et al., Noninvasive Experimental Evidence of the Linear Pore Size Dependence of Water Diffusion in Nanoconfinement, The Journal of Physical Chemistry Letters, vol.7, issue.3, pp.393-398, 2016.
DOI : 10.1021/acs.jpclett.5b02718

M. C. Bellisent-funel, S. H. Chen, and J. M. Zanotti, Single-particle dynamics of water molecules in confined space, Physical Review E, vol.98, issue.5, pp.4558-4569, 1994.
DOI : 10.1063/1.465031

S. H. Lee and P. J. Rossky, A comparison of the structure and dynamics of liquid water at hydrophobic and hydrophilic surfaces???a molecular dynamics simulation study, The Journal of Chemical Physics, vol.84, issue.4, pp.3334-3345, 1994.
DOI : 10.1002/ijch.198600030

H. F. Taylor, Proposed Structure for Calcium Silicate Hydrate Gel, Journal of the American Ceramic Society, vol.13, issue.2, pp.464-467, 1986.
DOI : 10.2465/ganko1941.79.267

C. Lester and R. G. Bryant, Water???proton nuclear magnetic relaxation in heterogeneous systems: Hydrated lysozyme results, Magnetic Resonance in Medicine, vol.29, issue.1, pp.143-153, 1991.
DOI : 10.1021/bk-1980-0127.ch006

C. Lester and R. G. Bryant, The magnetic-field dependence of proton spin relaxation in tissues, Magn. Reson. Imaging, vol.22, pp.117-126, 1991.

J. Korb, P. J. Mcdonald, L. Monteilhet, A. G. Kalinichev, and R. J. Kirkpatrick, Comparison of proton field-cycling relaxometry and molecular dynamics simulations for proton???water surface dynamics in cement-based materials, Cement and Concrete Research, vol.37, issue.3, pp.37-348, 2007.
DOI : 10.1016/j.cemconres.2006.02.009

J. Korb, L. Monteilhet, P. J. Mcdonald, and J. Mitchell, Microstructure and texture of hydrated cement-based materials: A proton field cycling relaxometry approach, Cement and Concrete Research, vol.37, issue.3, pp.37-295, 2007.
DOI : 10.1016/j.cemconres.2006.08.002

J. J. Thomas, H. M. Jennings, and A. J. Allen, Analysis of CSH gel and cement paste by small-angle-neutron scattering, Concr. SCI Eng, vol.1, pp.45-64, 1999.

R. L. Rarick, J. J. Thomas, B. J. Christensen, and H. M. Jennings, Deterioration of the nitrogen BET surface area of dried cement paste with storage time, Advanced Cement Based Materials, vol.3, issue.2, pp.72-75, 1996.
DOI : 10.1016/S1065-7355(96)90073-5

D. N. Winslow and S. Diamond, Specific Surface of Hardened Portland Cement Paste as Determined by Small-Angle X-Ray Scattering, Journal of the American Ceramic Society, vol.7, issue.3, pp.193-197, 1974.
DOI : 10.1016/0008-8846(72)90041-5

A. J. Allen, Time-resolved phenomena in cements, clays and porous rocks, Journal of Applied Crystallography, vol.24, issue.5, pp.624-634, 1991.
DOI : 10.1107/S0021889890012237

W. Halperin, J. Jehng, and Y. Song, Application of spin-spin relaxation to measurement of surface area and pore size distributions in a hydrating cement paste, Magnetic Resonance Imaging, vol.12, issue.2, pp.169-173, 1994.
DOI : 10.1016/0730-725X(94)91509-1

]. L. Barbic, I. Kocuvan, and R. Blinc, The Determination of Surface Development in Cement Pastes by Nuclear Magnetic Resonance, Journal of the American Ceramic Society, vol.30, issue.1, pp.65-90, 1982.
DOI : 10.1016/0370-1573(76)90021-1

N. Nestle, A simple semiempiric model for NMR relaxometry data of hydrating cement pastes, Cement and Concrete Research, vol.34, issue.3, pp.447-454, 2002.
DOI : 10.1016/j.cemconres.2003.08.023

R. M. Valckenborg, L. Pel, and K. Kopinga, Combined NMR cryoporometry and relaxometry, Journal of Physics D: Applied Physics, vol.35, issue.3, pp.249-253, 2002.
DOI : 10.1088/0022-3727/35/3/314

F. Sorrentino and R. Castanet, Application of thermal analysis to the cement industry, Journal of Thermal Analysis, vol.35, issue.6, pp.2147-2155, 1992.
DOI : 10.1680/adcr.1987.1.1.35

G. E. Pake, Nuclear Resonance Absorption in Hydrated Crystals: Fine Structure of the Proton Line, The Journal of Chemical Physics, vol.60, issue.4, pp.327-336, 1948.
DOI : 10.1021/ja01273a010

K. M. Song, J. Mitchell, H. Jaffel, and L. F. Gladden, Simultaneous monitoring of hydration kinetics, microstructural evolution, and surface interactions in hydrating gypsum plaster in the presence of additives, Journal of Materials Science, vol.90, issue.19, pp.45-5282, 2010.
DOI : 10.1007/s10853-010-4572-7

J. Korb and P. Levitz, Direct Probing of the Wettability of Plaster Pastes at the Nanoscale by Proton Field Cycling Relaxometry, AIP Conference Proceedings, pp.55-58, 2008.
DOI : 10.1063/1.3058546

P. E. Levitz, Random flights in confining interfacial systems, Journal of Physics: Condensed Matter, vol.17, issue.49, pp.4059-4074, 2005.
DOI : 10.1088/0953-8984/17/49/004

P. E. Levitz and J. Korb, Probing glass transition of clay colloids by NMR relaxometry: Interplay between fluid Brownian dynamics and particle jamming, Europhysics Letters (EPL), vol.70, issue.5, pp.684-689, 2005.
DOI : 10.1209/epl/i2004-10517-6

C. D. Pasquale, V. Marsala, A. E. Berns, M. Valagusa, A. Pozzi et al., Fast field cycling NMR relaxometry characterization of biochars obtained from an industrial thermochemical process, Journal of Soils and Sediments, vol.300, issue.2, pp.1211-1221, 2012.
DOI : 10.1007/s11104-007-9391-5

A. Gaspar, E. Zellermann, S. Lababidi, J. Reece, and W. Schrader, Characterization of Saturates, Aromatics, Resins, and Asphaltenes Heavy Crude Oil Fractions by Atmospheric Pressure Laser Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Energy & Fuels, vol.26, issue.6, pp.3481-3487, 2012.
DOI : 10.1021/ef3001407

O. C. Mullins, The Asphaltenes, Annual Review of Analytical Chemistry, vol.4, issue.1, pp.393-418, 2011.
DOI : 10.1146/annurev-anchem-061010-113849

J. Eyssautier, P. Levitz, D. Espinat, J. Jestin, J. Gummel et al., Insight into Asphaltene Nanoaggregate Structure Inferred by Small Angle Neutron and X-ray Scattering, The Journal of Physical Chemistry B, vol.115, issue.21, pp.6827-6837, 2011.
DOI : 10.1021/jp111468d

N. Vorapalawut, B. Nicot, A. L. Louis-joseph, and J. Korb, Probing Dynamics and Interaction of Maltenes with Asphaltene Aggregates in Crude Oils by Multiscale NMR, Energy & Fuels, vol.29, issue.8, pp.29-4911, 2015.
DOI : 10.1021/acs.energyfuels.5b01142

C. L. Guedes, E. D. Mauro, V. Antunes, and A. S. Mangrich, Photochemical weathering study of Brazilian petroleum by EPR spectroscopy, Marine Chemistry, vol.84, issue.1-2, pp.105-112, 2003.
DOI : 10.1016/S0304-4203(03)00114-2

L. Benamsili, J. Korb, G. Hamon, A. Louis-joseph, B. Bouyssière et al., Multi-dimensional Nuclear Magnetic Resonance Characterizations of Dynamics and Saturations of Brine/Crude Oil/Mud Filtrate Mixtures Confined in Rocks: The Role of Asphaltene, Energy & Fuels, vol.28, issue.3, pp.28-1629, 2014.
DOI : 10.1021/ef401871h

URL : https://hal.archives-ouvertes.fr/hal-01560496

G. Hirasaki, S. W. Lo, and Y. Zhang, NMR properties of petroleum reservoir fluids, Magnetic Resonance Imaging, vol.21, issue.3-4, pp.269-277, 2003.
DOI : 10.1016/S0730-725X(03)00135-8

J. Korb, N. Voralpalawut, B. Nicot, and R. G. Bryant, Relation and Correlation between NMR Relaxation Times, Diffusion Coefficients, and Viscosity of Heavy Crude Oils, The Journal of Physical Chemistry C, vol.119, issue.43, pp.24439-24446, 2015.
DOI : 10.1021/acs.jpcc.5b07510

O. C. Mullins, D. J. Seiffert, J. Y. Zuo, and M. Zeybeck, Clusters of Asphaltene Nanoaggregates Observed in Oilfield Reservoirs, Energy & Fuels, vol.27, issue.4, pp.1752-1761, 2013.
DOI : 10.1021/ef301338q

R. Rodgers, S. Rowland, D. Smith, M. Blakney, J. Chacon et al., Contributions of high resolution mass spectrometry to the field of petroleomics, Petrophase 2017, 2017.

B. Schuler, G. Meyer, D. Pena, O. C. Mullins, and L. Gross, Unraveling the Molecular Structures of Asphaltenes by Atomic Force Microscopy, Journal of the American Chemical Society, vol.137, issue.31, pp.9870-9876, 2015.
DOI : 10.1021/jacs.5b04056

A. C. Sodero, H. S. Silva, P. Guevara, B. Bouyssiere, J. Korb et al., Investigation of the Effect of Sulfur Heteroatom on Asphaltene Aggregation, Energy & Fuels, vol.30, issue.6, pp.30-4758, 2016.
DOI : 10.1021/acs.energyfuels.6b00757

URL : https://hal.archives-ouvertes.fr/hal-01536056

H. S. Silva, A. C. Sodero, B. Bouyssiere, H. Carrier, J. Korb et al., Molecular Dynamics Study of Nanoaggregation in Asphaltene Mixtures: Effects of the N, O, and S Heteroatoms, Energy & Fuels, vol.30, issue.7, pp.30-5656, 2016.
DOI : 10.1021/acs.energyfuels.6b01170

URL : https://hal.archives-ouvertes.fr/hal-01495764

P. Singer, Z. Chen, L. B. Alemany, and G. J. Hirasaki, NMR relaxation of polymeralkane mixes, a model systems for crude oils, SPWLA, in: 58th Ann, Log. Symposium, pp.1-18, 2017.

H. S. Silva, A. C. Sodero, J. Korb, A. Alfara, P. Giusti et al., The role of metalloporphyrins on the physical-chemical properties of petroleum fluids, Fuel, vol.188, pp.374-381, 2017.
DOI : 10.1016/j.fuel.2016.10.065

URL : https://hal.archives-ouvertes.fr/hal-01481296

M. Alizadehgiashi and J. M. Shaw, Fickian and Non-Fickian Diffusion in Heavy Oil + Light Hydrocarbon Mixtures, Energy & Fuels, vol.29, issue.4, pp.2177-2189, 2015.
DOI : 10.1021/ef502699c

J. W. Cahn and J. E. Hilliard, Free energy of a nonuniform system. I. Interfacial energy, J. Chem. Phys, vol.258, p.28, 1958.

M. D. Hürliman, M. Flaum, L. Venkataramanan, C. Flaum, R. Freedman et al., Diffusion-relaxation distribution functions of sedimentary rocks in different saturation states, Magnetic Resonance Imaging, vol.21, issue.3-4, pp.305-310, 2003.
DOI : 10.1016/S0730-725X(03)00159-0

L. Benamsili, J. Korb, G. Hamon, A. Louis-joseph, B. Bouyssière et al., Multi-dimensional Nuclear Magnetic Resonance Characterizations of Dynamics and Saturations of Brine/Crude Oil/Mud Filtrate Mixtures Confined in Rocks: The Role of Asphaltene, Energy & Fuels, vol.28, issue.3, pp.28-1629, 2014.
DOI : 10.1021/ef401871h

URL : https://hal.archives-ouvertes.fr/hal-01560496

M. D. Hürlimann, M. Flaum, L. Venkataramanan, C. Flaum, R. Freedman et al., Diffusion-relaxation distribution functions of sedimentary rocks in different saturation states, Magnetic Resonance Imaging, vol.21, issue.3-4, pp.305-310, 2003.
DOI : 10.1016/S0730-725X(03)00159-0

B. Nicot, Détermination de la viscosité des pétroles bruts lourds par relaxation RMN

A. R. Mutina and M. D. Hürlimann, Correlation of Transverse and Rotational Diffusion Coefficient:?? A Probe of Chemical Composition in Hydrocarbon Oils, The Journal of Physical Chemistry A, vol.112, issue.15, pp.3291-3301, 2008.
DOI : 10.1021/jp710254d

J. J. Chen, M. Hürlimann, J. Paulsen, D. Freed, S. Mandal et al., Dispersion of T1 and T2 NMR relaxation in crude oils, Chemphyschem Com, vol.15, pp.2671-2681, 2014.

E. C. Donaldson, R. D. Thomas, and P. B. Lorenz, Wettability Determination and Its Effect on Recovery Efficiency, Society of Petroleum Engineers Journal, vol.9, issue.01, 1969.
DOI : 10.2118/2338-PA

W. G. Anderson, Wettability Literature Survey- Part 2: Wettability Measurement, Journal of Petroleum Technology, vol.38, issue.11, pp.1125-1144, 1986.
DOI : 10.2118/13933-PA

M. Robin, Interfacial Phenomena: Reservoir Wettability in Oil Recovery, Oil & Gas Science and Technology, vol.56, issue.1, pp.55-62, 2001.
DOI : 10.2516/ogst:2001007

E. Amott, Observation relating to the wettability of porous rock, Trans, AIME Min. Metal. Eng, vol.216, pp.156-162, 1959.

W. J. Looyestijn, Wettability index determination from NMR logs, Petroph, pp.49-130, 2008.
DOI : 10.2118/93624-ms

M. Fleury and F. Deflandre, Quantitative evaluation of porous media wettability using NMR relaxometry, Magnetic Resonance Imaging, vol.21, issue.3-4, pp.385-387, 2003.
DOI : 10.1016/S0730-725X(03)00145-0

J. Korb, A. Louis-joseph, and L. Benamsili, Probing Structure and Dynamics of Bulk and Confined Crude Oils by Multiscale NMR Spectroscopy, Diffusometry, and Relaxometry, The Journal of Physical Chemistry B, vol.117, issue.23, pp.7002-7014, 2013.
DOI : 10.1021/jp311910t

C. L. Guedes, E. D. Mauro, V. Antunes, and A. S. Mangrich, Photochemical weathering study of Brazilian petroleum by EPR spectroscopy, Marine Chemistry, vol.84, issue.1-2, pp.105-112, 2003.
DOI : 10.1016/S0304-4203(03)00114-2

S. Stapf, A. Ordikhani-seyedlar, N. Ryan, C. Mattea, R. Kausic et al., Probing Maltene???Asphaltene Interaction in Crude Oil by Means of NMR Relaxation, Energy & Fuels, vol.28, issue.4, pp.28-2395, 2014.
DOI : 10.1021/ef4024788

J. Korb, B. Nicot, and I. Jolivet, Dynamics and wettability of petroleum fluids in shale oil probed by 2D T1-T2 and fast field cycling NMR relaxation, Microporous Mesoporous Mater, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01539764

A. Valori, Characterization of Cementitious Materials by 1 H NMR, 2009.

M. Fleury and M. F. Romero-sarmiento, Characterization of shales using T1???T2 NMR maps, Journal of Petroleum Science and Engineering, vol.137, pp.55-62, 2016.
DOI : 10.1016/j.petrol.2015.11.006

Z. Chen, P. M. Singer, and G. Hirasaki, Effects of bitumen extraction on the 2D NMR response of saturated kerogen isolates, 58th Ann. Logging Symp, 2017.

F. Dalas, J. Korb, S. Pourcher, A. Nonat, and D. Rinaldi, Surface Relaxivity of Cement Hydrates, The Journal of Physical Chemistry C, vol.118, issue.16, pp.8387-8396, 2014.
DOI : 10.1021/jp500055p

M. E. Curtiss, R. J. Ambrose, C. H. Sondergeld, and C. S. Rai, Structural Characterization of Gas Shales on the Micro- and Nano-Scales, Canadian Unconventional Resources and International Petroleum Conference, p.137693, 2010.
DOI : 10.2118/137693-MS

R. M. Daniel, R. V. Dunn, J. L. Finney, and J. C. Smith, The Role of Dynamics in Enzyme Activity, Annual Review of Biophysics and Biomolecular Structure, vol.32, issue.1, pp.32-69, 2003.
DOI : 10.1146/annurev.biophys.32.110601.142445

H. Frauenfelder and B. H. Mcmahon, Dynamics and function of proteins: The search for general concepts, Proceedings of the National Academy of Sciences, vol.95, issue.5, pp.95-4795, 1998.
DOI : 10.1073/pnas.95.5.2035

H. Frauenfelder, B. H. Mcmahon, R. H. Austin, K. Chu, and J. T. Groves, The role of structure, energy landscape, dynamics, and allostery in the enzymatic function of myoglobin, Proceedings of the National Academy of Sciences, vol.25, issue.4-5, pp.98-2370, 2001.
DOI : 10.1016/S0891-5849(98)00092-6

V. Reat, H. Patzelt, M. Ferrand, C. Pfister, D. Oesterhelt et al., Dynamics of different functional parts of bacteriorhodopsin: H-2H labeling and neutron scattering, Proceedings of the National Academy of Sciences, vol.1, issue.3, pp.95-4970, 1998.
DOI : 10.1016/S1097-2765(00)80041-6

J. A. Wand, Dynamic activation of protein function: a view emerging from NMR spectroscopy, Nature Structural Biology, vol.8, issue.11, pp.926-931, 2001.
DOI : 10.1038/nsb1101-926

B. Brooks and M. Karplus, Harmonic dynamics of proteins: normal modes and fluctuations in bovine pancreatic trypsin inhibitor., Proceedings of the National Academy of Sciences, vol.80, issue.21, pp.80-6571, 1983.
DOI : 10.1073/pnas.80.21.6571

N. Go, T. Noguti, and T. Nishikawa, Dynamics of a small globular protein in terms of low-frequency vibrational modes., Proceedings of the National Academy of Sciences, vol.80, issue.12, pp.80-3696, 1983.
DOI : 10.1073/pnas.80.12.3696

J. Korb and R. G. Bryant, The physical basis for the magnetic field dependence of proton spin-lattice relaxation rates in proteins, The Journal of Chemical Physics, vol.29, issue.23, pp.10964-10974, 2001.
DOI : 10.1002/mrm.1910350408

J. Korb and R. G. Bryant, Noise and Functional Protein Dynamics, Biophysical Journal, vol.89, issue.4, pp.2685-2692, 2005.
DOI : 10.1529/biophysj.105.060178

URL : https://doi.org/10.1529/biophysj.105.060178

D. M. Korzhnev, X. Salvatella, M. Vendruscolo, A. A. Nardo, A. R. Davidson et al., Low-populated folding intermediates of Fyn SH3 characterized by relaxation dispersion NMR, Nature, vol.12, issue.6999, pp.586-590, 2004.
DOI : 10.1016/S0022-2836(02)00944-0

]. B. Halle, V. P. Denisov, and K. Venu, Multinuclear Relaxation Dispersion Studies of Protein Hydration, Biological Magnetic Resonance, 1999.
DOI : 10.1007/0-306-47084-5_10

W. M. Shirley and R. G. Bryant, Proton-nuclear spin relaxation and molecular dynamics in the lysozyme-water system, Journal of the American Chemical Society, vol.104, issue.10, pp.2910-2918, 1982.
DOI : 10.1021/ja00374a034

T. Miyazawa, T. Shimanouchi, and S. Mizushima, ???Methylacetamide, The Journal of Chemical Physics, vol.74, issue.3, pp.611-616, 1958.
DOI : 10.1098/rspa.1956.0030

S. Alexander and R. Orbach, Density of states on fractals : ?? fractons ??, Journal de Physique Lettres, vol.46, issue.17, pp.625-631, 1982.
DOI : 10.1051/jphyslet:019820043017062500

URL : https://hal.archives-ouvertes.fr/jpa-00232103

S. Alexander, Vibrations of fractals and scattering of light from aerogels, Physical Review B, vol.10, issue.11, pp.7953-7965, 1989.
DOI : 10.1088/0305-4470/10/11/008

G. Diakova, Y. Goddard, J. Korb, and R. G. Bryant, Water and Backbone Dynamics in a Hydrated Protein, Biophysical Journal, vol.98, issue.1, pp.98-138, 2010.
DOI : 10.1016/j.bpj.2009.09.054

R. Kimmich and F. Winter, Double-diffusive fluctuations and the f^(3/4) law of proton spin-lattice relaxation in bioploymers, Progr. Colloid Polym. Sci, pp.71-66, 1985.

J. Korb, G. Diakova, and R. G. Bryant, Paramagnetic relaxation of protons in rotationally immobilized proteins, The Journal of Chemical Physics, vol.57, issue.13, pp.134910-134916, 2006.
DOI : 10.1126/science.231.4740.814

N. Bloembergen and L. O. Morgan, Proton Relaxation Times in Paramagnetic Solutions. Effects of Electron Spin Relaxation, The Journal of Chemical Physics, vol.5, issue.3, pp.842-850, 1961.
DOI : 10.1063/1.1742867

I. Bertini, J. Kowalewski, C. Luchinat, R. Nilsson, and G. Parigi, Nuclear spin relaxation in paramagnetic complexes of S=1: Electron spin relaxation effects, The Journal of Chemical Physics, vol.62, issue.13, pp.111-5795, 1999.
DOI : 10.1063/1.464848

D. Kruk and J. Kowalewski, Nuclear spin relaxation in paramagnetic systems (S???1) under fast rotation conditions, Journal of Magnetic Resonance, vol.162, issue.2, pp.229-240, 2003.
DOI : 10.1016/S1090-7807(03)00011-9

P. H. Fries, G. Ferrante, E. Belorizki, and S. Rast, The rotational motion and electronic relaxation of the Gd(III) aqua complex in water revisited through a full proton relaxivity study of a probe solute, The Journal of Chemical Physics, vol.19, issue.16, pp.8636-8644, 2003.
DOI : 10.1063/1.475903

M. W. Hodges, D. S. Cafiso, C. F. Polnaszek, C. C. Lester, and R. G. Bryant, Water translational motion at the bilayer interface: an NMR relaxation dispersion measurement, Biophysical Journal, vol.73, issue.5, p.73, 1997.
DOI : 10.1016/S0006-3495(97)78286-9

J. Crank, The Mathematics of Diffusion, 1975.

D. S. Grebenkov, NMR survey of reflected Brownian motion, Reviews of Modern Physics, vol.165, issue.3, pp.1077-1137, 2007.
DOI : 10.1063/1.1499956

R. Kimmich and G. Voigt, Nuclear magnetic relaxation dispersion in lecithin bilayers, Chemical Physics Letters, vol.62, issue.1, pp.181-183, 1979.
DOI : 10.1016/0009-2614(79)80438-8

R. Eberhard and F. Noack, Proton spin relaxation dispersioin studies of phospholipid membranes, J. Phys. Chem, vol.92, pp.2981-2987, 1988.

C. C. Lester and R. G. Bryant, Magnetically coupled paramagnetic relaxation agents, Magnetic Resonance in Medicine, vol.3, issue.2, pp.236-242, 1992.
DOI : 10.1002/mrm.1910030407

J. Korb, A. Delville, S. Xu, G. Demeulenaere, and G. Costa, Relative role of surface interactions and topological effects in nuclear magnetic resonance of confined liquids, The Journal of Chemical Physics, vol.13, issue.8, pp.7074-7081, 1994.
DOI : 10.1021/j100365a083

R. G. Bryant, D. Mendelson, and C. C. Lester, The magnetic field dependence of proton spin relaxation in tissues, Magnetic Resonance in Medicine, vol.86, issue.1, pp.199-117, 1991.
DOI : 10.1016/0375-9601(82)90548-5

S. H. Koenig, Molecular basis of magnetic relaxation of water protons of tissue, Academic Radiology, vol.3, issue.7, pp.597-606, 1996.
DOI : 10.1016/S1076-6332(96)80225-X

O. Neudert, H. Raich, C. Mattea, S. Stapf, and K. Münnemann, An Alderman???Grant resonator for S-Band Dynamic Nuclear Polarization, Journal of Magnetic Resonance, vol.242, pp.242-79, 2014.
DOI : 10.1016/j.jmr.2014.02.001

K. J. Pine, G. R. Davies, and D. J. Lurie, Field-cycling NMR relaxometry with spatial selection, Magnetic Resonance in Medicine, vol.43, issue.6, pp.1698-1702, 2010.
DOI : 10.1148/radiology.184.3.1509044

B. Kresse, M. Becher, A. F. Privalov, M. Hofmann, M. Vogel et al., Proton NMR at Larmor frequencies down to 3 Hz by means of fieldcycling techniques, 10th Conference on Fast Field Cycling NMR Relaxometry, 2017.